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Laxmi Narayan Tripathi Sourabh Barua 《Progress in Crystal Growth and Characterization of Materials》2019,65(4):100465
This review article covers the growth and characterization of two-dimensional (2D) crystals of transition metal chalcogenides, h-BN, graphene, etc. The chemical vapor transport method for bulk single crystal growth is discussed in detail. Top-down methods like mechanical and liquid exfoliation and bottom-up methods like chemical vapor deposition and molecular beam epitaxy for mono/few-layer growth are described. The optimal characterization techniques such as optical, atomic force, scanning electron, and Raman spectroscopy for identification of mono/few-layer(s) of the 2D crystals are discussed. In addition, a survey was done for the application of 2D crystals for both creation and deterministic transfer of single-photon sources and photovoltaic systems. Finally, the application of plasmonic nanoantenna was proposed for enhanced solar-to-electrical energy conversion and faster/brighter quantum communication devices. 相似文献
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相干anti-Stokes Raman散射(coherent anti-Stokes Raman scattering,CARS)技术作为一种非接触测量手段,已广泛应用于多种发动机模型燃烧室温度测量及地面试验.然而,目前的工作主要集中在稳态燃烧场温度的测量,缺乏用高分辨率的单脉冲来测量瞬变的燃烧火焰温度及组分浓度的研究.基于CARS理论,结合多参数拟合算法,开发了基于MATLAB的CARS光谱计算和拟合程序CARSCF;利用McKenna平面火焰炉在不同工况下进行了温度测量,并与DLR测量结果进行对比,结果显示开发的CARSCF具有较高的测量重复性和准确性;最后将CARS技术应用于测量超燃冲压发动机点火过程中的温度测量,获取了点火过程中的温度.结果显示,在来流Mach数为3的条件下,H2/air点火过程中温度呈现急剧上升然后缓慢下降,而CARS信号则呈现急剧上升然后急剧下降随后又缓慢上升的趋势,并且在点火过程中最高温度为1 511 K. 相似文献
4.
Two novel 2′-hydroxychalcone derivatives (i.e., M1 and M2) are explored in this work. We mainly focus on investigating the effects of photoexcitation on hydrogen bonds and on the excited-state intramolecular proton transfer (ESIPT) process. On the basis of calculations of electrostatic potential surface and intramolecular interactions, we verify the formation of hydrogen bond O1 H2···O3 in both S0 and S1 states. Exploring the ultraviolet–visible spectra in the liquid phase, our simulated results reappear in the experimental phenomenon. Analyzing molecular geometry and infrared stretching vibrational spectra, we confirm O1 H2···O3 is strengthened for both M1 and M2 in the S1 state. We further confirm that charge redistribution facilitates ESIPT tendency. Constructing potential energy curves, we find the ultrafast ESIPT behavior for M1, which is because of the deficiency of side hydroxyl moiety comparing with M2. This work makes a reasonable affiliation of the ESIPT mechanism for M1 and M2. We wish this paper could facilitate understanding these two novel systems and promote their applications. 相似文献
5.
Vitaly E. Matulis Ekaterina G. Ragoyja Oleg A. Ivashkevich 《International journal of quantum chemistry》2020,120(9):e26159
Boron-dipyrromethene dyes (BODIPY) are of great interest nowadays mostly due to their valuable optical properties. Nevertheless, no systematic research of the optical property dependence on the structure of dyes has been performed yet. In this work, analysis of the available quantum-chemical methods for BODIPY optical property calculations has been carried out. The accuracy of eight DFT functionals has been studied. The solvation effects upon excitation have been considered within two schemes. The methods that predict the absorption and emission spectra of BODIPY derivatives with high accuracy have been proposed. Using the suggested methods, the influence of nature of substituents and their position in the BODIPY core on the optical spectra of the dyes has been studied. A complex pattern of red- and blue-shifts in optical spectra in dependence of nature and position of substituents has been revealed. The results of this work provide the way for efficient design of BODIPY derivatives with desired optical properties. 相似文献
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Gold nanostars(Au NSs) are asymmetric anisotropic nanomaterials with sharp edge structure. As a promising branched nanomaterial, Au NS has excellent plasmonic absorption and scattering properties. In order to tune the plasmonic photothermal and surface-enhanced Raman scattering(SERS) activity of Au NSs to obtain the desired characteristics, the effects of reagents on the local surface plasmon resonance(LSPR) bands of Au NSs were studied and the morphology and size were regulated. Nanoparticles with different sharp edges were synthesized to make their local plasmon resonance mode tunable in the visible and near-infrared region. The effects of the number and sharpness of different tips under the control of AgNO3 on the photothermal response of Au NSs and the SERS activity and their mechanism were discussed in detail. The results show that as the length of the branch tip becomes longer and the sharpness increases, the plasmonic photothermal effect of Au NSs is strengthened, and the photothermal conversion efficiency is the highest up to 40% when the length of Au NSs is the longest. Au NSs with high SERS activity are used for the Raman detection substrate. Based on this property, the quantitative detection of the pesticide thiram is achieved. 相似文献
8.
Gas-phase 21Ne nuclear magnetic resonance spectra were measured at the natural abundance of 21Ne isotope for samples consisting of pressurized neon up to 60 bar at room temperature and applying the magnetic field of the strength B0 = 11.7574 T. It showed that the nuclear magnetic resonance frequency is linearly dependent on the density of gaseous neon. The resonance frequency was extrapolated to the zero-density point, and it permitted the determination of the 21Ne nuclear magnetic moment, μ(21Ne) = 0.6617774(10) μN. The present value of μ(21Ne) is not influenced by the bulk magnetic susceptibility of neon and interactions between neon atoms; therefore, it is more precise and reliable than the previous result obtained for μ(21Ne). 相似文献
9.
食源性致病微生物导致的食源性疾病已成为全球化的公共卫生问题。快速、有效地检测食源性致病微生物是实现食源性疾病预防与控制的关键环节,也是保障食品安全的技术关键。表面增强拉曼光谱(SERS)具有简单、快速、灵敏度高等优点,在食品安全、生物医学、环境监控等领域展现出良好的应用前景。介绍了近年来SERS在食源性致病微生物检测中的应用研究进展。对SERS技术概况、SERS增强理论及SERS增强基底进行了简要介绍,重点回顾了SERS在食源性致病微生物检测中的应用和发展现状。在食品安全分析方面,利用SERS与模式识别方法相结合对食品中常见食源性致病微生物能实现快速、有效鉴别,部分研究已应用于不同食品样品的分析,体现了SERS作为“指纹图谱”的分析优势;在医学诊断方面,SERS可对病理样品(如血液、尿液等)中食源性致病微生物进行快速检测,缩短了样本分析时间,使食源性疾病的快速诊断成为可能;随着微流控技术的发展,微流控平台结合SERS技术被称为“芯片实验室”应用于食源性致病微生物的检测,可提高分析的可控性,稳定性,特异性和灵敏度。通过对比分析,发现不同研究可采用不同分离方法、不同基底、不同目标捕获方式等实现了食源性致病微生物的检测,展示了不同方法间的差异性。已有研究表明了SERS在食源性致病微生物检测中应用可克服传统方法耗时等缺点,实现灵敏快速分析,为食品安全实时监控,食源性疾病即时诊断提供了有效的分析工具。同时,指出了SERS技术应用于食源性致病微生物分析依然面临很大挑战,(1)大多数研究并没有聚焦于实际样品,而标准培养液和实际样品的SERS检测存在较大差异,实际样品组分会对SERS响应产生干扰;(2)不同方法结果有较大差异,主要是由于纳米增强基底差异,吸附方式原理的差异,稳定性的差异等,因此需要更多深入研究进一步优化条件;(3)期望建立标准化的SERS方法替代传统技术,充分展示SERS作为新兴分析工具快速、灵敏、简捷的优势应用于食品安全,医学诊断等领域。将来,随着研究的深入及相关学科的发展,SERS作为极具潜力的快速分析工具,将在食品安全,生物医学等领域具有更广阔的应用前景。 相似文献
10.
Using first-principle calculations, mechanical properties, electronic structure, and Raman spectra of LiB6Si structure were investigated. The band structures calculated by GGA-PBE and HSE06 methods reveal that LiB6Si is an indirect band gap semiconductor. The band gap estimated by HSE06 method is about 2.24 eV, which is in good agreement with that of experimental value 2.27 eV. The calculated tensile stress-strain curves of LiB6Si reveal that [010] direction is the cleavage direction under tensile strains. The calculated Raman spectra of LiB6Si are also in good agreement with that of measured. The position of the band gap may provide a basis for further photocatalysis research on LiB6Si. 相似文献